<> endobj stream stream x�3R��2�35W(�2�300P@&�ҹ TCC’s Toluene Diisocyanate TDI 80-20 is a toxic and highly reactive organic compound. Chemical Product and Company Identification Product Name : Toluene Di Isocyanate Catalog Codes : SLT1264 CAS# : 584 -84 -9 RTECS : CZ6300000 TSCA : TSCA 8(b) inventory: Tolylene- 2, 4-diisocyanate CI# : Not available. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 03/21/2014 Revision date: … 5 0 obj After recovery and recycle of excess phosgene and the solvent the crude TDI is distilled to remove heavies (tar). Boiling Point. stream endstream Tolylene-2,4-diisocyanate 95% Synonym: 2,4-Diisocyanatotoluene, 4-Methyl-1,3-phenylene diisocyanate, 4-Methyl-m-phenylene diisocyanate, BASF LUPRANATE T80, TDI CAS Number 584-84-9. 9 0 obj Email. 3. endobj 3 0 obj 584-84-9. CZ6300000. �+R@&�ҹ 6f� Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. CAS No. The most common isomer of MDI is 4,4’-MDI. Toluene Diisocyanate. 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. <> TOLUENE DIISOCYANATE is explosive in the form of vapor-air mixture when exposed to heat, flame or sparks. Atlanta, GA: U.S. Department of Health and Human Services, Public Health Service. You can also browse global suppliers,vendor,prices,Price,manufacturers of TOLUENE DIISOCYANATE(26471-62-5). The two most common TDI isomers are 2,4-TDI and 2,6-TDI. DOT ID & Guide. Toluene Diisocyanate . <> EPA has developed a separate Action Plan for Methylene Diphenyl Diisocyanate (MDI) and its related compounds (PDF). �ʁt�1H��@aL*9�K?$��D�%_!�+�� � TCC’s TDI 80-20 is a mixture blend of 80% 2,4-toluene diisocyanate and 20% 2,6-toluene diisocyanate. endstream Toluene-2,4-diisocyanate. POTENTIAL PHYSICAL / CHEMICAL EFFECTS 1 0 obj $25.00. endstream 7 0 obj *aZe�f �t�u2��9�އ�\ء��L3�PB��ӄ�ψ�R�Y����d�8&yb�HƧ;����J�i�(���N�tǯDZ41��8ԈLi �' 4���!F3�3b�}c�Ɍ!L�#c �� mD���PN�F�C��L�t��aMHzy�S�ӵnZ��I���r"�J�l�R�"��`M-XNi:���Ţmw� #�IW�0#E���nO!톥�v��aL�{���>�"d����DZ�xiwCr�*2�P�e��}%����K���\R`��#E�7�'pGT�%JG'f��. TDI and MDI do not occur naturally in the environment. Material Safety Data Sheet (MSDS) - Toluene Di Isocyanate 1. The clear to pale yellow liquid organic compound is toxic, has a sharp odor, and is highly reactive. Chemsrc provides toluene diisocyanate(CAS#:26471-62-5) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. 15 0 obj CAS# 26471-62-5 101-68-8 September 2015. endobj Uses advised against Food, drug, pesticide or biocidal product use. 17034 Classification. 16 0 obj 584-84-9 RTECS No. "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��“7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k�������u��=���� ��f.�蟗��y_�j6}Yɗ���2�3 �> q�B�-��i����%�m���Si��=�J{����������uL�Ã{��!��B�431 �� \�~��iww�#��ׅLJe��~�i�]z��p������w��h��킑�K�����|g�����ާ ����dw����e[�Ӭ-�����ݞSL2���&�˺���m�"[��\�{�{�Qv���>K�?K�]�K��|�l��'*�|�-LwO�����ozs�Ro���8��M�o��O}W���:ߊ4v�- �:��������̀D�>�b���~�A>�Yg�jw ���m��O�/��9�߈0����? %PDF-1.4 endstream endobj Undergoes potentially violent polymerization reaction with strong bases or acyl chlorides. endstream <> Toluene Safety Data Sheet according to Federal Register / Vol. 13 0 obj Unit. endobj Toluene Diisocyanate is primarily used as a chemical intermediate in the production of polyurenthane products. endstream C 9 H 6 N 2 O 2 C 15 H 10 N 2 O 2 ToxGuideTM. TOLUENE-2,4-DIISOCYANATE is explosive in the form of vapor when exposed to heat, flame or sparks. 1 0 obj TDI is a clear, colorless to pale yellow liquid. # D-5836-02N. �ʁt�1H��@aL*9�K?$��\�%_!�+�� �� : AC208040000; AC208040010; AC208040050 CAS-No 91-08-7 Synonyms 2-Methyl-1,3-phenylene diisocyanate Recommended Use Laboratory chemicals. Toluene diisocyanate is an organic compound with the formula CH3C6H3(NCO)2. Potentially violent polymerization reaction with strong bases or acyl chlorides. It is used to make Polyurethane foams, elastomers and coatings. endobj The assessment is summarized in this information sheet (formerly public summary) and has not changed. Add to Cart Add. 4 0 obj toluene 2,4-diisocyanate. ChEBI CHEBI:53557: A toluene meta-diisocyanate in which the isocyanato groups are at positions 2 and 6 relative to the methyl group on the benzene ring. endobj C 9 H 6 N 2 O 2 C 15 H 10 N 2 O 2. The chemical formula for TDI is CH 3 C 6 H 3 (NCO) 2.TDI is often marketed as TDI 80/20. endobj 1.1±0.1 g/cm3. �ʁt�1H��@aL*9�K?$��T�%_!�+�� �� Revised IDLH: 2.5 ppm Basis for revised IDLH: The revised IDLH for toluene-2,4-diisocyanate is 2.5 ppm based on acute inhalation toxicity data in animals [Duncan et al. The two different forms are isomers. Storage Condition Storage. MDL number MFCD00002011. Catalog Number Cat. Profile for Toluene Diisocyanate and Methylenediphenyl Diisocyanate (Draft for public comment). 1. It is produced on a large scale, accounting for 34.1% of the global isocyanate market in 2000, second only to MDI. CAS Number. %PDF-1.4 12 0 obj Toluene diisocyanate, TDI. stream Two of the six possible isomers are commercially important: 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). Synonyms & Trade Names TDI, 2,4-TDI, 2,4-Toluene diisocyanate CAS No. Toluene diisocyanate (TDI) is an organic compound with the formula CH3C6H3 (NCO)2. x�3R��2�35W(�2�300P@&�ҹ Synonym: 2,4-Diisocyanatotoluene, 4-Methyl-m-phenylene diisocyanate, Tolylene 2,4-diisocyanate Empirical Formula (Hill Notation): C 9 H 6 N 2 O 2 Molecular Weight: 174.16 SAFETY DATA SHEET Revision Date 21-Feb-2020 Revision Number 2 1. 174.156. Reacts with water to liberate carbon dioxide. /Length 5632 >> TOLUENE 108-88-3 100% * All concentrations are percent by weight unless material is a gas. Uses advised against Food, drug, pesticide or biocidal product use. 4 0 obj 1962]. Beilstein/REAXYS Number 744602 . >> endobj endstream endobj Since in sensitized individuals, even concentrations below the OSHA PEL are capable of triggering the allergic response, the revised IDLH has not been based on data obtained from the exposures of individuals or … stream Two of the six possible isomers are commercially important: 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). KONNATE T-80 KONNATE T-80 is a mixture of 80% 2,4-toluene diisocyanate and 20% 2,6-toluene diisocyanate. �ʁt�1H��@aL*9�K?$��H�%_!�+�� C� HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). Sensitive individuals may exhibit skin rash, wheezing, tightness of the chest, and difficulty breathing that may progress to a life-threatening inability to breathe. Identification Product Name Toluene-2,4-diisocyanate, 80%, remainder 2,6-diisocyanate Cat No. Toluylene diisocyanate (mixture of isomeres) for synthesis. The section in this information sheet entitled "Preventive actions and reducing risk" communicates updates in risk management activities, namely: 1. X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? <> Toluene diisocyanate TECHNICAL DATA SHEET KONNATE TDI Page 1 of 3 DESCRIPTION KONNATE T-80 contains the 2,4- and 2,6-isomer of toluene diisocyanate. Molecular Weight. Details of the supplier of the safety data sheet Visit ChemicalBook To find more TOLUENE DIISOCYANATE(26471-62-5) information like chemical properties,Structure,melting point,boiling point,density,molecular formula,molecular weight, physical properties,toxicity information,customs codes. ���������Tڵ�{�>�w���*^�?xp�__/����� �� Q�0�;&Pg{'jDŽO��/�\��. EC Number 209-544-5. Certified Reference Material. << x�3R��2�35W(�2�300P@&�ҹ stream x�3R��2�35W(�2�300P@&�ҹ 11 0 obj Gas concentrations are in percent by volume. x�3R��2�35W(�2�300P@&�ҹ 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. Diisocyanate . <> - Find MSDS or SDS, a COA, data sheets and more information. Tel: 02 8064 2333 Email: admin@labtech.com.au Compare. CAS# 91-08-7. … 100 mg. Price (USD) Price. <> Toluene di isocyanate (TDI) is an organic compound with the formula CH3C6H3(NCO)2. https://www.epa.gov/.../fact-sheet-toluene-diisocyanate-tdi-and-related 8 0 obj 26471-62-5, EC Number 247-722-4. REASON FOR CITATION * Toluene-2,4-Diisocyanate is on the Hazardous Substance List because it is regulated by OSHA and cited by 14 0 obj 251.0±0.0 °C at 760 mmHg. Chronic inhalation may cause lung damage. endobj Reaction with aniline may generate enough heat to ignite unreacted portion and surrounding materials. endobj The Final Screening Assessment for toluene diisocyanates (TDIs) was published on July 5, 2008 under the Challenge Initiative of the Chemicals Management Plan (CMP). <> for. endobj <> <> /Producer(Sub Systems, Inc.)/CreationDate(D:20200221214048+05'00')/ModDate(D:20200221214048+05'00')/Creator(Sub Systems, Inc.) Synonym : Toluene-2,4-diisocyanate endobj Toluene Diisocyanate (TDI) is a colorless to pale yellow flammable liquid with a sharp pungent odour. x�3R��2�35W(�2�300P@&�ҹ The Toluene Diisocyanates (TDI) Action Plan (PDF) addresses EPA’s review of Toluene Diisocyanate (TDI) and related compounds, CASRNs 91-08-7, 584-84-9, 26471-62-5, 9017-01-0, 26747-90-0, and 26603-40-7. Explore information about Air pollutants, contaminants and studies being done Toluene diisocyante (TDI, CAS no 26471-62-5) is produced by phosgenation of MTD in a solvent. Less widely used, but still important, are the aliphatic diisocyanates, including hexamethylene diisocyanate (HDI), hydrogenated MDI (H12MDI), and isophorone diisocyanate (IPDI). 77, No. Diphenylmethane 4,4'-diisocyanate SDS Safety Data Sheet for Diphenylmethane 4,4'-diisocyanate 820797. Reaction with water liberates carbon dioxide. : 36733 Synonyms No information available Recommended Use Laboratory chemicals. stream Details of the supplier of the safety data … %���� 2078 156. <> Formula. This product is used in the preparation of polyurethane foams, prepolymers and elastomers. Number of Components Comps. It exists in two forms; 2,4-toluene diisocyanate and 2,6-toluene diisocyanate. Material Safety Data Sheet or SDS for Diphenylmethane 4,4'-diisocyanate 820797 from MilliporeSigma for download or viewing in the browser. stream endobj Publication of a final pollution prevention planning notice. SAFETY DATA SHEET Revision Date 25-Apr-2019 Revision Number 5 1. Ambient (>5 °C) Safety Data Sheet SDS. The most widely used aromatic diisocyanates are toluene diisocyanate (TDI) and methylene diphenyl diisocyanate (MDI). �ʁt�1H��@aL*9�K?$��X�%_!�+�� a� 17 0 obj Articles of toluene diisocyanate are included as well. Toluene diisocyanate, oligomeric reaction products with 2,2'-oxydiethanol and propylidenetrimethanol Regulatory process names 2 IUPAC names 5 Other identifiers 1 Print infocard 10 0 obj Related Pages. Toluene-2,4-Diisocyanate is a colorless to pale yellow liquid with a strong fruity odor. <> Linear Formula CH 3 C 6 H 3 (NCO) 2. Toluene Diisocyanate Revision Date: 06-June-2017 Version 1.1 1. <> Supplier and Substance Identification Product Information Product name: Toluene Diisocyanate Description: Polyurethane component, industrial chemicals Recommended use of the chemical and restrictions on use Recommended use Plasticizer Uses advised against None known Potential explosion if stored in polyethylene containers due to absorption of water through the plastic. 2,6-Toluene diisocyanate. Postal Address Labtech Service & Supplies PO Box 453, Windsor NSW 2756. Two of the six possible isomers are commercially important: 2,4-TDI and 2,6-TDI. Toluene diisocyanate. �ʁt�1H��@aL*9�K?$��L�%_!�+�� �� Density. There are several forms of TDI and MDI, which are called isomers. Toluene Diisocyanate (TDI) is a potent skin and respiratory allergic sensitizer. x��\�g�Y�"���*��A�������{���mb��Y���evg �.�0��(�^)�6-���4��QC�Ƣ����hZmTy$��w�=�������M�����|��{��7&yFy���cr����JfV:7&D� m�S�! <> Listed by IARC as a group 2B – Possible Human Carcinogen. From the tar the remaining TDI is recovered to maximize yield. <> stream MDI is a light yellow crystalline solid. 6 0 obj Identification Product Name Tolylene 2,6-diisocyanate Cat No. <>/Group <> endobj 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. <> Molecular Weight 174.16 . x�3R��2�35W(�*T0P�R0T(�Y@���@QC= P A�J��� �1Tp�W� A toluene meta-diisocyanate in which the isocyanato groups are at positions 2 and 6 relative to the methyl group on the benzene ring. 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Details of the global isocyanate market in 2000, second only to MDI aniline may generate enough heat ignite... Explosive in the form of vapor-air mixture when exposed to heat, flame or sparks Diphenylmethane... For download or viewing in the browser & Supplies PO Box 453, NSW... Cas Number 584-84-9 weight unless material is considered to be hazardous according to regulatory guidelines see... Cas No 26471-62-5 ) this information Sheet ( MSDS ) - toluene Di (... H 6 N 2 O 2 ToxGuideTM, Price, manufacturers of toluene diisocyanate and 20 % 2,6-toluene diisocyanate (..., BASF LUPRANATE T80, TDI CAS Number 584-84-9 Use Laboratory chemicals: 06-June-2017 Version 1.1 1 Q�0� &! Common TDI isomers are commercially important: 2,4-TDI and 2,6-TDI ( CAS: 91-08-7.! Heavies ( tar ) TDI 80-20 is a clear, colorless to pale yellow liquid organic compound skin respiratory. To be hazardous according to regulatory guidelines ( see ( M ) Section! Compound with the formula CH3C6H3 ( NCO ) 2 and Methylene Diphenyl diisocyanate ( MDI and... A gas the assessment is summarized in this information Sheet entitled `` Preventive actions reducing... - toluene Di isocyanate ( TDI ) is a mixture blend of 80 %, 2,6-diisocyanate... 26, 2012 / Rules and Regulations Date of issue: 03/21/2014 Date. Ac208040050 CAS-No 91-08-7 Synonyms 2-Methyl-1,3-phenylene diisocyanate Recommended Use Laboratory chemicals SDS for Diphenylmethane 4,4'-diisocyanate 820797 U.S. Department of toluene diisocyanate sds! Undergoes potentially violent polymerization reaction with strong bases or acyl chlorides the 2,4- and 2,6-isomer toluene. And 20 % 2,6-toluene diisocyanate diisocyanate Recommended Use Laboratory chemicals after recovery recycle...: 06-June-2017 Version 1.1 1, prices, Price, manufacturers of toluene diisocyanate Draft... Portion and surrounding materials TDI, CAS No 26471-62-5 ) is produced on a large scale, accounting 34.1. For 34.1 % toluene diisocyanate sds the global isocyanate market in 2000, second only to MDI diisocyanate CAS No ) Data... In a solvent 36733 Synonyms No information available Recommended Use Laboratory chemicals °C ) Safety Data for... ) - toluene Di isocyanate 1 toluene Safety Data Sheet according to regulatory guidelines ( (! Preventive actions and reducing risk '' communicates updates in risk toluene diisocyanate sds activities,:... Explore information about Air pollutants, contaminants and studies being done toluene diisocyanate No 26471-62-5 ) is a blend! 2,4-Toluene diisocyanate and 2,6-toluene diisocyanate %, remainder 2,6-diisocyanate Cat No to 29CFR1910/1200 and GHS Rev produced by phosgenation MTD. Data Sheet KONNATE TDI Page 1 of 3 DESCRIPTION KONNATE T-80 contains the 2,4- and 2,6-isomer of toluene diisocyanate diisocyanate!: 91-08-7 ) 2,4-Diisocyanatotoluene, 4-Methyl-1,3-phenylene diisocyanate, TDI CAS Number 584-84-9 Regulations Date of issue: Revision... Names TDI, 2,4-TDI, 2,4-toluene diisocyanate CAS No are 2,4-TDI and 2,6-TDI ( CAS: 91-08-7 ) *?. Is often marketed as TDI 80/20 the crude TDI is recovered to maximize yield the Safety Sheet! Ghs Rev done toluene diisocyanate is primarily used as a chemical intermediate in the of. Draft for public comment ) polyurethane foams, prepolymers and elastomers not changed liquid with a sharp odour... 2.Tdi is often marketed as TDI 80/20 global isocyanate market in 2000, second only to MDI admin @ toluene...